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每周分享7.22

閱讀:637      發布時間:2014-7-22
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   今天給大家分享的是20141月份 Applied Catalysis B: Environmental》上發表的一篇名為:Activation of carbon-supported platinum catalysts by sodium for the low-temperature water-gas shift reaction

 

文章摘要如下:

The activation of multi-walled carbon nanotube-supported platinum catalysts for the low-temperature water-gas shift reaction is demonstrated by the addition of sodium. Nitric acid oxidation of the carbon nanotubes allows for the addition of sodium through ion-exchange and creates anchoring sites for platinum. We show that an oxidized platinum state is stabilized by the presence of sodium. Evidence for a sodium-promoted Pt-(OH)x active site is given through XPS analysis of the catalysts before and after reaction and confirmed by CO-TPR. Removal of the oxygen groups and partial removal of sodium by annealing the Na-modified carbon nanotubes to 800 °C in inert atmosphere creates a surface on which Pt is initially very active, but of lower stability due to the absence of a sufficient number of surface sodium anchoring sites.

 

該文章中材料表征采用的是美國麥克儀器AutoChem 2920

 

詳情可參考下面鏈接:

http://www.sciencedirect.com/science/article/pii/S0926337313004323

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